ChemInform Abstract: Silica Gel Promotes Reductions of Aldehydes and Ketones by N‐Heterocyclic Carbene Boranes.
Identifieur interne : 007F35 ( Main/Exploration ); précédent : 007F34; suivant : 007F36ChemInform Abstract: Silica Gel Promotes Reductions of Aldehydes and Ketones by N‐Heterocyclic Carbene Boranes.
Auteurs : Tsuyoshi Taniguchi [États-Unis] ; Dennis P. Curran [États-Unis]Source :
- ChemInform [ 0931-7597 ] ; 2012-12-25.
English descriptors
- KwdEn :
- Aldehyde, Aldehyde group, Ambient, Ambient conditions, Borane, Boranes, Boron hydrides, Carbene, Carbene borane, Carbene boranes, Chem, Cheminform, Curran, Dimethyl, Dimethyl analogue, Gmbh, Keto, Keto group, Ketone, Kgaa, Klein cheminform, Lett, Rapid reduction, Secondary alcohols, Sio2, Taniguchi, Univ, Verlag, Verlag gmbh, Weinheim, Weinheim cheminform.
- Teeft :
- Aldehyde, Aldehyde group, Ambient, Ambient conditions, Borane, Boranes, Boron hydrides, Carbene, Carbene borane, Carbene boranes, Chem, Cheminform, Curran, Dimethyl, Dimethyl analogue, Gmbh, Keto, Keto group, Ketone, Kgaa, Klein cheminform, Lett, Rapid reduction, Secondary alcohols, Sio2, Taniguchi, Univ, Verlag, Verlag gmbh, Weinheim, Weinheim cheminform.
Abstract
One, two, or all three of the boron hydrides of carbene borane NHC and its dimethyl analogue can be transferred to the aldehydes and ketones to give primary and secondary alcohols under ambient conditions and in the presence of SiO2, which is crucial for the rapid reduction.
Url:
DOI: 10.1002/chin.201252072
Affiliations:
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Le document en format XML
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<term>Carbene</term>
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<term>Curran</term>
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<term>Dimethyl analogue</term>
<term>Gmbh</term>
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<front><div type="abstract" xml:lang="en">One, two, or all three of the boron hydrides of carbene borane NHC and its dimethyl analogue can be transferred to the aldehydes and ketones to give primary and secondary alcohols under ambient conditions and in the presence of SiO2, which is crucial for the rapid reduction.</div>
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